(R)-(-)-Benzyl glycidyl ether

Product Name: (R)-(-)-Benzyl glycidyl ether
CAS No.: 14618-80-5
Chemical Name: (R)-(-)-Benzyl glycidyl ether
Synonyms: tert-butyl 3-oxoazepane-1-carboxylate;azepan-3-one;dicyclopropylmethanamine;tert-butyl 3-hydroxyazepane-1-carboxylate;2-(trimethylsilyl)ethanamine;benzyl piperidin-3-ylcarbamate;(2R)-2-(Benzyloxymethyl)oxirane;benzyl 3-hydroxypiperidine-1-carboxylate;tert-butyl 4-hydroxyazepane-1-carboxylate;5-TMP,2Na
CBNumber: CB9320637
Molecular Formula: C10H12O2
Formula Weight: 164.2
MOL File: 14618-80-5.mol

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(R)-(-)-Benzyl glycidyl ether Property

Melting point:: 88-93°C
Boiling point:: 130 °C (0.1 mmHg)
alpha: -5.4 º (c=5 in toluene)
Density: 1.077 g/mL at 25 °C(lit.)
refractive index: n20/D 1.517(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
form: paste (yellow)
Specific Gravity: 1.077
color: Colorless to Almost colorless
optical activity: [α]20/D 5.4°, c = 5 in toluene
Water Solubility: Soluble in water.
BRN: 3588399
CAS DataBase Reference: 14618-80-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-37/39
RIDADR: NA 1993 / PGIII
WGK Germany: 3
RTECS: TX2860020
HS Code: 29109000
Toxicity: mic-sat 660 nmol/plate MUREAV 298,197,1993

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 791547
Product name: Titania paste, transparent
Packaging: 10G
Price: $225
Updated: 2024/03/01

Sigma-Aldrich

Product number: 791547
Product name: Titania paste, transparent
Packaging: 20G
Price: $326
Updated: 2024/03/01

Sigma-Aldrich

Product number: 720429
Product name: 1H-Pyrazol-3-ylboronic acid hydrate
Packaging: 1g
Price: $251
Updated: 2023/06/20

Sigma-Aldrich

Product number: 363529
Product name: (R)-(?)-Glycidyl benzyl ether
Purity: 99%
Packaging: 1g
Price: $42.4
Updated: 2023/06/20

TCI Chemical

Product number: B2238
Product name: Benzyl (R)-(-)-Glycidyl Ether
Purity: >98.0%(GC)
Packaging: 1g
Price: $19
Updated: 2024/03/01

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(R)-(-)-Benzyl glycidyl ether Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Used in the preparation of the lactone fragment of compactin and mevinolin. Chiron in the preparation of syn-1,3-polyols, dideoxynucleosides, and a spiroacetal cyanohydrin.

Synthesis Reference(s)

Tetrahedron Letters, 21, p. 4807, 1980 DOI: 10.1016/0040-4039(80)80145-6

General Description

1H-Pyrazol-3-ylboronic acid hydrate can be used as a reactant in the Suzuki-Miyaura coupling reaction to synthesize pyrazole derivatives by reacting with different aryl halides over the palladium catalyst.

Safety Profile

Mutation data reported. Whenheated to decomposition it emits acrid smoke andirritating vapors.

Purification Methods

This ether in EtOAc is dried (Na2SO4), then purified by flash chromatography using pet ether/EtOAc (5:1) as eluent. The ether distils through a short path distillation apparatus (Kügelrohr) as a colourless liquid. Alternatively, dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and purify by silica gel chromatography. [Anisuzzamen & Owen J Chem Soc 1021 1967, Takano et al. Heterocycles 1 6 381 1981, Lipshutz et al. Org Synth 69 82 1990, Takano et al. Synthesis 539 1989, Honda et al. Chem Pharm Bull Jpn 39 1385 1991, Beilstein 12 IV 2277.]

(R)-(-)-Benzyl glycidyl ether Preparation Products And Raw materials

Raw materials

Sodium hydride (S)-Oxiranemethanol N,N-Dimethylformamide Benzyl bromide Ethyl acetate PETROLEUM ETHER

Preparation Products

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(R)-(-)-Benzyl glycidyl ether Suppliers

Americas 1 Belgium 1 China 228 Europe 4 France 1 Germany 5 India 8 Japan 5 South Korea 2 Switzerland 2 The Netherlands 1 United Kingdom 9 United States 42 Global 309

HBCChem, Inc.

Tel: +1-510-219-6317
Fax: +1-650-486-1361
Email: sales@hbcchem.com
Country: United States
ProdList: 10658
Advantage: 60

Accela ChemBio Inc.

Tel: (+1)-858-699-3322
Fax: (+1)-858-876-1948
Email: info@accelachem.com
Country: United States
ProdList: 19965
Advantage: 58

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63711
Advantage: 58

Aladdin Scientific

Tel: +1-833-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57511
Advantage: 58

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View Lastest Price from (R)-(-)-Benzyl glycidyl ether manufacturers

Hebei Duling International Trade Co. LTD

Product: (R)-(-)-Benzyl glycidyl ether 14618-80-5
Price: US $51.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2023-03-16

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R)-()-Glycidyl benzyl ether 14618-80-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (R)-(-)-Benzyl glycidyl ether 14618-80-5
Price: US $9.80/KG
Min. Order: 1g
Purity: ≥99%
Supply Ability: 100kg
Release date: 2020-01-12

14618-80-5, (R)-(-)-Benzyl glycidyl etherRelated Search:

Epichlorohydrin Benzyl chloride Benzyl isocyanate Dimethyl ether Glycidyl acrylate Isobutylene oxide Styrene oxide ETHYLENE OXIDE (R)-Styrene oxide Benzyl alcohol Ethylbenzene Propylene oxide Benzyl nicotinate Benzyl benzoate Benzyl VERPROSIDE (R)-(+)-Trityl glycidyl ether Diethyl ether

(R)-(-)-BENZYL GLYCIDYL ETHER

(R)-BENZYL GLYCIDYL ETHER

(R)-BENZYLOXYMETHYL-OXIRANE

RARECHEM AK HZ 0049

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azepan-3-one

benzyl 3-aminoazepane-1-carboxylate

benzyl 3-hydroxyazepane-1-carboxylate

benzyl 3-hydroxypiperidine-1-carboxylate

benzyl 3-oxoazepane-1-carboxylate

benzyl 4-aminoazepane-1-carboxylate

benzyl 4-hydroxyazepane-1-carboxylate

benzyl 4-oxoazepane-1-carboxylate

benzyl azepan-4-ylcarbamate

benzyl piperidin-3-ylcarbamate

dicyclopropylmethanamine

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[Ir(dtbbpy)(ppy)2][PF6] AldrichCPR

[Ir{dF(CF3)ppy}2(dtbpy)]PF6 AldrichCPR

1-(2,2,2-trifluoroethyl)piperazine AldrichCPR

1-(Tetrahydro-2H-pyran-2-yl)-3-pyrazole boronic acid MIDA ester 97%

1H-Pyrazol-3-ylboronic acid hydrate

2-Hexyl-4-pentynoic acid AldrichCPR

3-(2-thienyl)pyrazole AldrichCPR

3-(TrifluoroMethyl)-1,2,4-triazolo[4,3-a]piperazine hydrochloride AldrichCPR

4'-(1H-1,2,4-triazol-1-yl)phenol AldrichCPR

4-(2-Chlorophenoxy)piperidine hydrochloride AldrichCPR

4-(DiphenylaMino)phenylboronic acid pinacol ester 95%

Azide-fluor 488 >=90% (HPLC)

BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct May contain up to 1 Mole equivalent of MTBE, 97%

CdSeS/ZnS alloyed quantuM dots COOH functionalized, fluorescence laMbdaeM 525 nM, 6 nM diaMeter, 1 Mg/ML in H2O

CdSeS/ZnS alloyed quantuM dots COOH functionalized, fluorescence laMbdaeM 575 nM, 6 nM diaMeter, 1 Mg/ML in H2O

Dibenzocyclooctyne-acid storage teMp.: -20C, 95%

Graphene oxide 2 Mg/ML, dispersion in H2O

Graphene oxide sheets

Isoflurane AldrichCPR

N,N-bis(2-hydroxyethyl)-1,4-phenylenediaMine sulfate AldrichCPR

PCy3 Pd G2 95%

PlatinuM on graphitized carbon extent of labeling: 20 wt. % loading

R-95 RhaMnolipid 95%, AldrichCPR

SodiuM undecylenate AldrichCPR

SYLGARD(R) 184 5 g clip-pack

spiro[4.5]-decan-1-one

2-AMINO-3-HYDROXY-3-METHYLPROPANENITRILE

2-AMINO-3-HYDROXY-4-METHYLPROPANENITRILE

(R)-Benzyl glycidyl ether 98%

(2R)-2-[(Phenylmethoxy)methyl]oxirane

3-epoxy-1-(benzyloxy)-(r)-propan

3-epoxy-1-(benzyloxy)-(s)-propan

(-)-BENZYL (R)-GLYCIDYL ETHER

BENZYL (R)-(-)-GLYCIDYL ETHER

BENZYL (R)-GLYCIDYL ETHER